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Stock Option Plans and Stock Based Compensation Level 4 (Details) - Summary of Existing Stock Based Compensation Plans - USD ($)
$ in Millions
12 Months Ended
Dec. 31, 2015
Dec. 31, 2014
Dec. 31, 2013
Stock based compensation plans [Line Items]      
Term used in valuation model 30 years   30 years
Stock-based compensation expense $ 1 $ 1 $ 3
Share-based Compensation Arrangement by Share-based Payment Award, Expiration Date Nov. 01, 2010    
Option Term 8 years 30 days    
shares outstanding 82,556,847 82,556,847  
Employee Service Share-based Compensation, Nonvested Awards, Total Compensation Cost Not yet Recognized $ 17    
Compensation Expense to be recognized ratably $ 1    
Employee Service Share-based Compensation, Nonvested Awards, Total Compensation Cost Not yet Recognized, Period for Recognition 1 year    
Compensation Expense to be recognized upon an initial public offering $ 17    
Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan - Tranche B & C [Member]      
Stock based compensation plans [Line Items]      
Aggregate Grant Date Fair Value     $ 2
Share-based Compensation Arrangement by Share-based Payment Award, Fair Value Assumptions, Expected Term 22 years   21 years 4 months 24 days
Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan - Tranche A Options [Member]      
Stock based compensation plans [Line Items]      
Aggregate Grant Date Fair Value $ 2   $ 6
Share-based Compensation Arrangement by Share-based Payment Award, Fair Value Assumptions, Risk Free Interest Rate     2.17%
Share-based Compensation Arrangement by Share-based Payment Award, Fair Value Assumptions, Expected Term     6 years 3 months
Share-based Compensation Arrangement by Share-based Payment Award, Fair Value Assumptions, Expected Volatility Rate     37.50%
Share-based Compensation Arrangement by Share-based Payment Award, Fair Value Assumptions, Expected Dividend Rate     0.00%
Resolution Performance 2000 Stock Option Plan - Tranche A options [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 17,849    
Resolution Performance 2000 Stock Option Plan - Tranche B options [Member] [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 35,729    
Resolution Performance 2000 Non-Employee Directors Option Plan [Member]      
Stock based compensation plans [Line Items]      
Share-based Compensation Arrangement by Share-based Payment Award, Expiration Date Nov. 01, 2010    
Option Term 8 years 30 days    
shares outstanding 286,626    
Resolution Specialty Materials 2004 Stock Option Plan [Member]      
Stock based compensation plans [Line Items]      
Share-based Compensation Arrangement by Share-based Payment Award, Expiration Date Oct. 01, 2014    
Option Term 8 years 30 days    
Number of Shares Authorized 1,027,197    
Resolution Specialty Materials 2004 StockOption Plan - Tranche A options [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 21,873    
Resolution Specialty Materials 2004 Stock Option Plan - Tranche B performance options [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 43,748    
Resolution Specialty Materials 2004 Stock Option Plan - Director options [Member] [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 42,799    
BHI Acquisition Corp. 2004 Stock Incentive Plan [Member]      
Stock based compensation plans [Line Items]      
Share-based Compensation Arrangement by Share-based Payment Award, Expiration Date Aug. 01, 2014    
Option Term 10 years    
Number of Shares Authorized 3,670,635    
BHI Acquisition Corp. 2004 Stock Incentive Plan - Trance A options [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 864,463    
BHI Acquisition Corp. 2004 Stock Incentive Plan - Trance B options [Member] [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 864,463    
BHI Acquisition Corp. 2004 Stock Incentive Plan - Director options [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 56,282    
Hexion LLC 2007 Long-Term Incentive Plan [Member]      
Stock based compensation plans [Line Items]      
Share-based Compensation Arrangement by Share-based Payment Award, Expiration Date Apr. 01, 2017    
Number of Shares Authorized 1,700,000    
Hexion LLC 2007 Long-Term Incentive Plan - Options to purchase units [Member]      
Stock based compensation plans [Line Items]      
Option Term 8 years    
shares outstanding 230,500    
Hexion LLC 2007 Long-Term Incentive Plan - Restricted Stock Units [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 50,000    
Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan [Member]      
Stock based compensation plans [Line Items]      
Share-based Compensation Arrangement by Share-based Payment Award, Expiration Date Feb. 01, 2021    
Option Term 10 years    
Number of Shares Authorized 20,800,000    
Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan - Tranche B & C Options [Member]      
Stock based compensation plans [Line Items]      
Aggregate Grant Date Fair Value     $ 3
Share-based Compensation Arrangement by Share-based Payment Award, Fair Value Assumptions, Expected Term 6 years 2 months 12 days   9 years 2 months 12 days
Share-based Compensation Arrangement by Share-based Payment Award, Fair Value Assumptions, Expected Dividend Rate 0.00%   0.00%
Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan - Tranche A RDU's [Member] [Member] [Member]      
Stock based compensation plans [Line Items]      
Aggregate Grant Date Fair Value $ 4   $ 4
Minimum [Member] | Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan - Tranche B & C Options [Member]      
Stock based compensation plans [Line Items]      
Share-based Compensation Arrangement by Share-based Payment Award, Fair Value Assumptions, Risk Free Interest Rate 0.11%   0.16%
Share-based Compensation Arrangement by Share-based Payment Award, Fair Value Assumptions, Expected Volatility Rate 28.10%   34.60%
Maximum [Member] | Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan - Tranche B & C Options [Member]      
Stock based compensation plans [Line Items]      
Share-based Compensation Arrangement by Share-based Payment Award, Fair Value Assumptions, Risk Free Interest Rate 2.06%   3.44%
Share-based Compensation Arrangement by Share-based Payment Award, Fair Value Assumptions, Expected Volatility Rate 35.50%   41.70%
Tranche A Options [Member] | Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 2,317,726    
Tranche A RDUs [Member] | Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 7,041    
Tranche B Options [Member] | Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 1,158,856    
Tranche B RDUs [Member] | Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 386,280    
Tranche C Options [Member] | Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 1,158,856    
Tranche C RDU's [Member] | Momentive Performance Materials Holdings LLC 2011 Equity Incentive Plan [Member]      
Stock based compensation plans [Line Items]      
shares outstanding 386,280