Transaction Valuation(1)

Amount of Filing Fee(1)(2)

$19,065,207,127

$585,302


Amount Previously Paid		Filing Party:
Form or Registration No.:		Date Field:

Amount Previously Paid

Filing Party:

Form or Registration No.:

Date Field:

Exhibit (a)(5)(PP)

News release…

Date: 2 November 2007

Ref: PR567g

Rio Tinto Offer for Alcan – 90% threshold reached

Rio Tinto today announces that approximately 90.2% (339,339,000 shares) of the outstanding common shares of Alcan Inc. (“Alcan”) have been validly deposited and taken up under the offer by Rio Tinto Canada Holding Inc. (“RTCH”) to acquire all of the shares of Alcan (the “Offer”).

RTCH is now entitled to acquire all the remaining Alcan shares by way of compulsory acquisition under the Canada Business Corporations Act. RTCH will exercise these rights promptly after the expiry of the Offer.

All additional validly deposited shares during the balance of the Offer period will be taken up daily and payment for such shares will be made to the depositary within two business days of take-up. Shares covered by notices of guaranteed delivery will be taken up when the certificates representing them are delivered to the depositary. The Offer expires at 6:00 p.m. (Canadian Eastern Time) on November 8, 2007.

Cont.../

Rio Tinto plc 6 St James’s Square London SW1Y 4LD

Telephone 020 7930 2399 Fax 020 7930 3249

REGISTERED OFFICE: 6 St James’s Square London SW1Y 4LD Registered in England No. 719885

About Rio Tinto

Rio Tinto is a leading international mining group headquartered in the UK, combining Rio Tinto plc, a London listed company, and Rio Tinto Limited, which is listed on the Australian Securities Exchange.

Rio Tinto’s business is finding, mining, and processing mineral resources. Major products are aluminium, copper, diamonds, energy (coal and uranium), gold, industrial minerals (borax, titanium dioxide, salt, talc) and iron ore. Activities span the world but are strongly represented in Australia and North America with significant businesses in South America, Asia, Europe and southern Africa.

For further information or a copy of reports filed under Canadian securities legislation, please contact:

Rio Tinto Canada Holding Inc.
770 Sherbrooke Street West, Suite 1800
Montreal, Quebec H3A1G1

Or please contact:

Media Relations, London		Media Relations, Australia

Christina Mills Office: +44 (0) 20 8080 1306 Mobile: +44 (0) 7825 275 605 Nick Cobban Office: +44 (0) 20 8080 1305 Mobile: +44 (0) 7920 041 003		Ian Head Office: +61 (0) 3 9283 3620 Mobile: +61 (0) 408 360 101 Amanda Buckley Office: +61 (0) 3 9283 3627 Mobile: +61 (0) 419 801 349

Investor Relations, London Nigel Jones Office: +44 (0) 20 7753 2401 Mobile: +44 (0) 7917 227 365 David Ovington Office: +44 (0) 20 7753 2326 Mobile: +44 (0) 7920 010 978		Investor Relations, Australia Dave Skinner Office: +61 (0) 3 9283 3628 Mobile: +61 (0) 408 335 309 Investor Relations, North America Jason Combes Office: +1 (0) 801 685 4535 Mobile: +1 (0) 801 558 2645

Email: questions@riotinto.com

Website: www.riotinto.com High resolution photographs available at: www.newscast.co.uk

Additional information

The offer to purchase all of the issued and outstanding common shares of Alcan for US$101 per common share in a recommended, all cash transaction (the “Offer”) is being made by Rio Tinto Canada Holding Inc. (the “Offeror”), an indirect wholly-owned subsidiary of Rio Tinto. The address of the Offeror is 770 Sherbrooke Street West, Suite 1800, Montreal, Quebec, H3A 1G1.

The Offer represents a total consideration for Alcan common shares of approximately US$38.1 billion.

The subsequent offering period has commenced and the Offer is open for acceptance until 6.00 p.m., Canadian Eastern Time, on November 8, 2007, unless extended.

This announcement is for information purposes only and does not constitute or form part of any offer or invitation to purchase, otherwise acquire, subscribe for, sell, otherwise dispose of or issue, or any solicitation of any offer to sell, otherwise dispose of, issue, purchase, otherwise acquire or subscribe for, any security. The Offer (as the same may be varied or extended in accordance with applicable law) is being made exclusively by means of, and subject to the terms and conditions set out in, the offer and takeover bid circular delivered to Alcan and filed with Canadian provincial securities regulators and the United States Securities and Exchange Commission (the “SEC”) and mailed to Alcan shareholders.

The release, publication or distribution of this announcement in certain jurisdictions may be restricted by law and therefore persons in such jurisdictions into which this announcement is released, published or distributed should inform themselves about and observe such restrictions.

In connection with the Offer, an offer and takeover bid circular as well as ancillary documents such as a letter of transmittal and a notice of guaranteed delivery have been filed with the Canadian securities regulatory authorities and the SEC and an Alcan directors’ circular with respect to the Offer has also been filed. A Tender Offer statement on Schedule TO (the “Schedule TO”) and a Solicitation/Recommendation Statement on Schedule 14D-9 (the “Schedule 14D-9”) has also been filed with the SEC.

SHAREHOLDERS OF ALCAN ARE URGED TO READ THE OFFER AND TAKEOVER BID CIRCULAR (INCLUDING THE LETTER OF TRANSMITTAL AND NOTICE OF GUARANTEED DELIVERY), THE SCHEDULE TO (INCLUDING THE OFFER AND TAKEOVER BID CIRCULAR, LETTER OF TRANSMITTAL AND RELATED TENDER OFFER DOCUMENTS) AND THE SCHEDULE 14D-9 AS THEY CONTAIN IMPORTANT INFORMATION ABOUT THE OFFER.

The offer and takeover bid circular as well as other materials filed with the Canadian securities regulatory authorities are available electronically without charge at www.sedar.com. The Schedule TO and the Schedule 14D-9 are available electronically without charge at the SEC’s website, www.sec.gov. Materials filed with the SEC or the Canadian securities regulatory authorities may also be obtained without charge at Rio Tinto’s website, www.riotinto.com.

While the Offer is being made to all holders of Alcan common shares, this announcement does not constitute an offer or a solicitation in any jurisdiction in which such offer or solicitation is unlawful. The Offer is not being made in, nor will deposits be accepted in, any jurisdiction in which the making or acceptance thereof would not be in compliance with the laws of such jurisdiction. However, the Offeror may, in its sole discretion, take such action as it may deem necessary to extend the Offer in any such jurisdiction.

The Offer is made to holders in France of Alcan common shares admitted to trading on Euronext-Paris. An announcement including the main information relating to the Offer documents has been prepared and released pursuant to article 231-24 of the AMF General Regulation and contains information relating to how and in which time limit Alcan shareholders residing in France can accept this Offer. The offer document and the

announcement prepared pursuant to article 231-24 of the AMF General Regulation, as amended on 17 September 2007, 23 and 24 October 2007 are available free of charge to the holders of Alcan Shares registered with Euroclear France who request it from Citi France, Global Transaction Services, Operations department, 19 le Parvis la Défense 7, 92073 Paris la Défense. They are also available on the internet at the following address: www.computershare.com/Rio-AlcanFrenchofferdocument.

The Offer is made to holders in Belgium of Alcan common shares and/or certificates admitted to trading on Euronext Brussels (the “IDRs”). A Belgian supplement, addressing issues specific to holders of Alcan common shares and/or IDRs in Belgium (the “Belgian Supplement”) was approved by the Belgian Banking, Finance and Insurance Commission (the “BFIC”) on 2 August 2007. A notice of extension of the Offer was approved by the BFIC on 18 September 2007 (the “First Supplement”). A second notice of extension of the Offer was approved by the BFIC on 23 October 2007 (the “Second Supplement”). The offer document, the Belgian Supplement , the First Supplement and the Second Supplement are available free of charge to the investors in Belgium who request it from the Belgian branch of Citibank International plc, Department GTS Operations, 4th floor, boulevard Général Jacques 263G, 1050 Brussels. They are also available on the internet at the following address: www.computershare.com/Rio-AlcanBelgianofferdocument

(a)(1)(A)°		Circular, dated July 24, 2007.
(a)(1)(B)°		Form of Letter of Transmittal.
(a)(1)(C)°		Form of Notice of Guaranteed Delivery.
(a)(1)(D)°		Form of Letter to Brokers, Dealers, Commercial Banks, Trust Companies and Other Nominees.
(a)(1)(E)°		Form of Letter to Clients for use by Brokers, Dealers, Commercial Banks, Trust Companies and Other Nominees.
(a)(5)(A)°		Summary Advertisement in The Wall Street Journal, dated July 24, 2007.
(a)(5)(B)°		Press release announcing commencement of the Offer, dated July 24, 2007.
(a)(5)(C)°		Transcript of interview with Bloomberg UK, dated July 12, 2007.
(a)(5)(D)°		Transcript of interview with CNBC Europe, dated July 12, 2007.
(a)(5)(E)°		Transcript of interview with CNN International, dated July 12, 2007.
(a)(5)(F)°		Transcript of interview with CNBC US, dated July 19, 2007.
(a)(5)(G)°		Management slide presentation by Rio Tinto plc, dated August 2, 2007.
(a)(5)(H)°		Script of management slide presentation by Rio Tinto plc, dated August 2, 2007.
(a)(5)(I)°		News release announcing half-year results, dated August 2, 2007.
(a)(5)(J)°		Transcript of interview with BNN, dated July 18, 2007.
(a)(5)(K)°		Transcript of interview with the Australian Broadcasting Corporation, dated July 23, 2007.
(a)(5)(L)°		Memorandum to managers of Rio Tinto and Alcan, dated August 2, 2007.
(a)(5)(M)°		Press release relating to the Offer, dated August 7, 2007.
(a)(5)(N)°		Frequently Asked Questions about the Rio Tinto Offer for Alcan Inc., dated August 20, 2007.
(a)(5)(O)°		Press release announcing extraordinary general meetings, dated August 24, 2007.
(a)(5)(P)°		Press release announcing US antitrust approval, dated August 27, 2007.
(a)(5)(Q)°		Press release announcing completion of loan syndication for financing of Alcan acquisition, dated August 30, 2007.
(a)(5)(R)°		Press release announcing Canadian Competition Act clearance, dated August 30, 2007.
(a)(5)(S)°		Press release announcing Rio Tinto plc Extraordinary General Meeting, dated September 14, 2007.
(a)(5)(T)°		Notice of extension of the Offer, dated September 17, 2007.
(a)(5)(U)°		Letter to shareholders of Alcan announcing the extension of the Offer, dated September 17, 2007.
(a)(5)(V)°		Press release announcing the extension of the Offer, dated September 17, 2007.
(a)(5)(W)°		Press release announcing approval of the acquisition of Alcan by Rio Tinto shareholders, dated September 28, 2007.
(a)(5)(X)°		Press release announcing European competition clearance, dated October 2, 2007.
(a)(5)(Y)°		Press release announcing Australian Competition & Consumer Commission clearance, dated October 3, 2007.
(a)(5)(Z)°		Press release announcing French Government approval, dated October 4, 2007.
(a)(5)(AA)°		Press release announcing Exon-Florio clearance received, dated October 5, 2007.
(a)(5)(BB)°		Press release announcing Australian Foreign Investment Review Board approval, dated October 9, 2007.
(a)(5)(CC)°		Press release announcing Proposed Aluminium Business Executive Management Team, dated October 10, 2007.
(a)(5)(DD)°		Press release announcing receipt of Investment Canada Act approval, dated October 18, 2007.
(a)(5)(EE)°		Joint press release by Rio Tinto and Alcan, dated October 18, 2007, announcing receipt of regulatory approvals.
(a)(5)(FF)°		Advertisement dated October 19, 2007.
(a)(5)(GG)°		Press release announcing changes to the Rio Tinto Board of Directors, dated October 24, 2007.
(a)(5)(HH)°		Press release announcing the commencement of the Subsequent Offering Period, dated October 23, 2007.
(a)(5)(II)°		Press release announcing Alcan's joining of Rio Tinto, dated October 25, 2007.
(a)(5)(JJ)°		Presentation to Managers, dated October 25, 2007.

(a)(5)(KK)°		Q&A list relating to the Offer, dated October 25, 2007.
(a)(5)(LL)°		Letter to employees relating to the Offer, dated October 25, 2007.
(a)(5)(MM)°		Fact sheet relating to the Offer, dated October 25, 2007.
(a)(5)(NN)°		Press release announcing the acquisition of additional shares of Alcan, dated October 25, 2007.
(a)(5)(OO)°		Notice of extension of the Offer, dated October 25, 2007.
(a)(5)(PP)		Press release announcing the acquisition of 90% of the shares of Alcan by Rio Tinto Canada Holding Inc., dated November 2, 2007.
(b)(1)°		Facility Agreement, dated July 12, 2007, among Rio Tinto, Credit Suisse, Deutsche Bank AG, London Branch, The Royal Bank of Scotland plc, and Societe Generale.
(d)(1)°		Support Agreement, dated July 12, 2007, among Alcan, the Offeror and Rio Tinto.
(d)(2)°		English language translation of undertakings and confirmations made by Rio Tinto and Offeror to the Government of Quebec and Alcan, dated July 11, 2007.
(d)(3)°		Confidentiality Agreement, dated April 11, 2007 between Alcan and Rio Tinto.
(d)(4)°		Amendment to Confidentiality Agreement, dated June 25, 2007.
(d)(5)°		Standstill Agreement, dated June 13, 2007, between Alcan and Rio Tinto.
(d)(6)°		Amendment to Support Agreement, dated July 20, 2007, among Alcan, the Offeror and Rio Tinto.
(g)°		None.
(h)°		None.

Date: November 5, 2007	RIO TINTO PLC
	By:	/s/ GUY ELLIOTT
	Name: Title:	Guy Elliott Finance Director
	RIO TINTO CANADA HOLDING INC.
	By:	/s/ IAN RATNAGE
	Name: Title:	Ian Ratnage Director

(a)(1)(A)°		Circular, dated July 24, 2007.
(a)(1)(B)°		Form of Letter of Transmittal.
(a)(1)(C)°		Form of Notice of Guaranteed Delivery.
(a)(1)(D)°		Form of Letter to Brokers, Dealers, Commercial Banks, Trust Companies and Other Nominees.
(a)(1)(E)°		Form of Letter to Clients for use by Brokers, Dealers, Commercial Banks, Trust Companies and Other Nominees.
(a)(5)(A)°		Summary Advertisement in The Wall Street Journal, dated July 24, 2007.
(a)(5)(B)°		Press release announcing commencement of the Offer, dated July 24, 2007.
(a)(5)(C)°		Transcript of interview with Bloomberg UK, dated July 12, 2007.
(a)(5)(D)°		Transcript of interview with CNBC Europe, dated July 12, 2007.
(a)(5)(E)°		Transcript of interview with CNN International, dated July 12, 2007.
(a)(5)(F)°		Transcript of interview with CNBC US, dated July 19, 2007.
(a)(5)(G)°		Management slide presentation by Rio Tinto plc, dated August 2, 2007.
(a)(5)(H)°		Script of management slide presentation by Rio Tinto plc, dated August 2, 2007.
(a)(5)(I)°		News release announcing half-year results, dated August 2, 2007.
(a)(5)(J)°		Transcript of interview with BNN, dated July 18, 2007.
(a)(5)(K)°		Transcript of interview with the Australian Broadcasting Corporation, dated July 23, 2007.
(a)(5)(L)°		Memorandum to managers of Rio Tinto and Alcan, dated August 2, 2007.
(a)(5)(M)°		Press release relating to the Offer, dated August 7, 2007.
(a)(5)(N)°		Frequently Asked Questions about the Rio Tinto Offer for Alcan Inc., dated August 20, 2007.
(a)(5)(O)°		Press release announcing extraordinary general meetings, dated August 24, 2007.
(a)(5)(P)°		Press release announcing US antitrust approval, dated August 27, 2007.
(a)(5)(Q)°		Press release announcing completion of loan syndication for financing of Alcan acquisition, dated August 30, 2007.
(a)(5)(R)°		Press release announcing Canadian Competition Act clearance, dated August 30, 2007.
(a)(5)(S)°		Press release announcing Rio Tinto plc Extraordinary General Meeting, dated September 14, 2007.
(a)(5)(T)°		Notice of extension of the Offer, dated September 17, 2007.
(a)(5)(U)°		Letter to shareholders of Alcan announcing the extension of the Offer, dated September 17, 2007.
(a)(5)(V)°		Press release announcing the extension of the Offer, dated September 17, 2007.
(a)(5)(W)°		Press release announcing approval of the acquisition of Alcan by Rio Tinto shareholders, dated September 28, 2007.
(a)(5)(X)°		Press release announcing European competition clearance, dated October 2, 2007.
(a)(5)(Y)°		Press release announcing Australian Competition & Consumer Commission clearance, dated October 3, 2007.
(a)(5)(Z)°		Press release announcing French Government approval, dated October 4, 2007.
(a)(5)(AA)°		Press release announcing Exon-Florio clearance received, dated October 5, 2007.
(a)(5)(BB)°		Press release announcing Australian Foreign Investment Review Board approval, dated October 9, 2007.
(a)(5)(CC)°		Press release announcing Proposed Aluminium Business Executive Management Team, dated October 10, 2007.
(a)(5)(DD)°		Press release announcing receipt of Investment Canada Act approval, dated October 18, 2007.
(a)(5)(EE)°		Joint press release by Rio Tinto and Alcan, dated October 18, 2007, announcing receipt of regulatory approvals.
(a)(5)(FF)°		Advertisement dated October 19, 2007
(a)(5)(GG)°		Press release announcing changes to the Rio Tinto Board of Directors, dated October 24, 2007.
(a)(5)(HH)°		Press release announcing the commencement of the Subsequent Offering Period, dated October 23, 2007.
(a)(5)(II)°		Press release announcing Alcan's joining of Rio Tinto, dated October 25, 2007.
(a)(5)(JJ)°		Presentation to Managers, dated October 25, 2007.

(a)(5)(KK)°		Q&A list relating to the Offer, dated October 25, 2007.
(a)(5)(LL)°		Letter to employees relating to the Offer, dated October 25, 2007.
(a)(5)(MM)°		Fact sheet relating to the Offer, dated October 25, 2007.
(a)(5)(NN)°		Press release announcing the acquisition of additional shares of Alcan, dated October 25, 2007.
(a)(5)(OO)°		Notice of extension of the Offer, dated October 25, 2007.
(a)(5)(PP)		Press release announcing the acquisition of 90% of the shares of Alcan by Rio Tinto Canada Holding Inc., dated November 2, 2007.
(b)(1)°		Facility Agreement, dated July 12, 2007, among Rio Tinto, Credit Suisse, Deutsche Bank AG, London Branch, The Royal Bank of Scotland plc, and Societe Generale.
(d)(1)°		Support Agreement, dated July 12, 2007, among Alcan, the Offeror and Rio Tinto.
(d)(2)°		English language translation of undertakings and confirmations made by Rio Tinto and Offeror to the Government of Quebec and Alcan, dated July 11, 2007.
(d)(3)°		Confidentiality Agreement, dated April 11, 2007 between Alcan and Rio Tinto.
(d)(4)°		Amendment to Confidentiality Agreement, dated June 25, 2007.
(d)(5)°		Standstill Agreement, dated June 13, 2007, between Alcan and Rio Tinto.
(d)(6)°		Amendment to Support Agreement, dated July 20, 2007, among Alcan, the Offeror and Rio Tinto.
(g)°		None.
(h)°		None.