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Inventories - Schedule of Inventory Components (Detail) (USD $)
In Millions, unless otherwise specified
Dec. 31, 2013
Dec. 31, 2012
Inventory Disclosure [Abstract]    
Finished goods $ 578 $ 542
Work-in-process 828 866
Bauxite and alumina 581 618
Purchased raw materials 474 536
Operating supplies 244 263
Inventories, total $ 2,705 $ 2,825