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Income Taxes - Reconciliation of U.S. Federal Statutory Rate to Alcoa's Effective Tax Rate for Continuing Operations (Detail)
12 Months Ended
Dec. 31, 2013
Dec. 31, 2012
Dec. 31, 2011
Income Tax Disclosure [Abstract]      
U.S. federal statutory rate 35.00% 35.00% 35.00%
Taxes on foreign operations (0.30%) (0.10%) (11.00%)
Permanent differences on restructuring and other charges and asset disposals (0.80%) 10.80%  
Audit and other adjustments to prior years' accruals (0.90%) 3.50% (1.10%)
Noncontrolling interests (3.10%) 3.80% 0.80%
Statutory tax rate and law changes 0.60% (0.40%) 0.80%
Changes in valuation allowances (23.20%) 15.20% 2.30%
Impairment of goodwill (33.30%)    
Amortization of goodwill related to intercompany stock sales/reorganizations 1.10% (7.70%) (2.80%)
Change in legal structure of investment   (4.10%)  
Interest income related to income tax positions   (1.30%) (0.20%)
Company-owned life insurance/split-dollar net premiums 1.10% (3.90%) (0.20%)
Other 0.20% (0.80%) 0.40%
Effective tax rate (23.60%) 50.00% 24.00%