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Inventories - Schedule of Inventory Components (Detail) (USD $)
In Millions, unless otherwise specified
Dec. 31, 2012
Dec. 31, 2011
Inventory [Line Items]    
Finished goods $ 542 $ 537
Work-in-process 866 911
Bauxite and alumina 618 656
Purchased raw materials 536 532
Operating supplies 263 263
Inventories, total $ 2,825 $ 2,899