XML 27 R5.htm IDEA: XBRL DOCUMENT v2.4.0.8
Consolidated Statements of Stockholders' Equity (USD $)
Total
Preferred Stock [Member]
Common Stock [Member]
Paid in Capital [Member]
Accumulated Deficit [Member]
Beginning Balance at Jan. 17, 2002          
Issuance to founding shareholders     $ 6,000 $ (6,000)  
Issuance to founding shareholders, shares     6,000,000    
Sale of stock 25,000   50 24,950  
Sale of stock, shares     50,000    
Issuance of stock to employees 932,000   510 931,490  
Issuance of stock to employees, shares     510,000    
Issuance of stock for services 360,000   120 359,880  
Issuance of stock for services, shares     120,000    
Net loss (1,316,198)       (1,316,198)
Ending Balance at Apr. 23, 2002 802   6,680 1,310,320 (1,316,198)
Ending Balance, shares at Apr. 23, 2002     6,680,000    
Shares issued in reverse merger (3,645)   266 (3,911)  
Shares issued in reverse merger, shares     265,763    
Purchase and retirement of stock (48,000)   (400) (47,600)  
Purchase and retirement of stock, shares     (400,000)    
Stock issued for acquisition of Valley Pharmaceuticals 12,226,320   500 12,225,820  
Stock issued for acquisition of Valley Pharmaceuticals, shares     500,007    
Exercise of warrants 453   453    
Issuance of stock for services 5,144,000   1,900 5,142,100  
Exercise of warrants, shares     452,919    
Warrants issued in connection with convertible debt 126,587     126,587  
Issuance of stock for services, shares     1,900,000    
Stock and warrants issued for acquisition of Pure-ific 27,000   25 26,975  
Stock and warrants issued for acquisition of Pure-ific, shares     25,000    
Net loss (5,749,937)       (5,749,937)
Ending Balance at Dec. 31, 2002 11,723,580   9,424 18,780,291 (7,066,135)
Ending Balance, shares at Dec. 31, 2002     9,423,689    
Stock to be issued for services 281,500     281,500  
Issuance of warrants for services 145,479     145,479  
Issuance of stock pursuant to Regulation S 380,347   680 379,667  
Issuance of stock pursuant to Regulation S, shares     679,820    
Issuance of stock for services 239,800   764 239,036  
Issuance of stock for services, shares     764,000    
Employee compensation from stock options 34,659     34,659  
Beneficial conversion related to convertible debt 601,000     601,000  
Net loss (3,155,313)       (3,155,313)
Ending Balance at Dec. 31, 2003 10,251,052   10,868 20,461,632 (10,221,448)
Ending Balance, shares at Dec. 31, 2003     10,867,509    
Issuance of warrants for services 495,480     495,480  
Issuance of stock pursuant to Regulation S 793,137   2,469 790,668  
Issuance of stock pursuant to Regulation S, shares     2,469,723    
Exercise of warrants 5,000   133 4,867  
Issuance of stock for services 449,923   734 449,190  
Exercise of warrants, shares     132,608    
Issuance of stock for services, shares     733,872    
Employee compensation from stock options 15,612     15,612  
Issuance of convertible debt with warrants 105,250     105,250  
Issuance of stock and warrants pursuant to Regulation D 1,288,861   1,930 1,286,930  
Issuance of stock and warrants pursuant to Regulation D, shares     1,930,164    
Beneficial conversion related to convertible debt 360,256     360,256  
Repurchase of beneficial conversion feature (258,345)     (258,345)  
Net loss (4,344,525)       (4,344,525)
Ending Balance at Dec. 31, 2004 9,161,701   16,134 23,711,540 (14,565,973)
Ending Balance, shares at Dec. 31, 2004     16,133,876    
Issuance of stock for interest payable 196,031   264 195,767  
Issuance of stock for interest payable, shares     263,721    
Issuance of warrants for services 1,534,405     1,534,405  
Issuance of warrants for contractual obligations 985,010     985,010  
Exercise of warrants and stock options 1,439,795   1,572 1,438,223  
Exercise of warrants and stock options, shares     1,571,849    
Issuance of stock for services 152,285   227 152,058  
Issuance of stock for services, shares     226,733    
Employee compensation from stock options 15,752     15,752  
Issuance of convertible debt with warrants 1,574,900     1,574,900  
Issuance of stock and warrants pursuant to Regulation D 6,513,176   6,221 6,506,955  
Issuance of stock and warrants pursuant to Regulation D, shares     6,221,257    
Beneficial conversion related to interest expense 39,529     39,529  
Preferred stock/Debt conversions into common stock 3,049,362   3,405 3,045,957  
Preferred stock/Debt conversions into common stock, shares     3,405,541    
Beneficial conversion related to convertible debt 1,633,176     1,633,176  
Repurchase of beneficial conversion feature (144,128)     (144,128)  
Net loss (11,763,853)       (11,763,853)
Ending Balance at Dec. 31, 2005 14,387,141   27,823 40,689,144 (26,329,826)
Ending Balance, shares at Dec. 31, 2005     27,822,977    
Issuance of stock for interest payable 183,596   195 183,401  
Issuance of stock for interest payable, shares     194,327    
Issuance of warrants for services 370,023     370,023  
Exercise of warrants and stock options 1,189,816   1,246 1,188,570  
Exercise of warrants and stock options, shares     1,245,809    
Issuance of stock for services 676,743   719 676,024  
Issuance of stock for services, shares     719,246    
Employee compensation from stock options 1,862,456     1,862,456  
Issuance of stock and warrants pursuant to Regulation D 4,130,421   10,092 4,120,329  
Issuance of stock and warrants pursuant to Regulation D, shares     10,092,495    
Beneficial conversion related to interest expense 16,447     16,447  
Preferred stock/Debt conversions into common stock 1,576,336   2,377 1,573,959  
Preferred stock/Debt conversions into common stock, shares     2,377,512    
Net loss (8,870,579)       (8,870,579)
Ending Balance at Dec. 31, 2006 15,522,400   42,452 50,680,353 (35,200,405)
Ending Balance, shares at Dec. 31, 2006     42,452,366    
Issuance of stock for interest payable 1,258   1 1,257  
Issuance of stock for interest payable, shares     1,141    
Issuance of warrants for services 472,635     472,635  
Exercise of warrants and stock options 3,985,641   3,929 3,981,712  
Exercise of warrants and stock options, shares     3,928,957    
Issuance of stock for services 298,950   150 298,800  
Issuance of stock for services, shares     150,000    
Employee compensation from stock options 2,340,619     2,340,619  
Issuance of stock and warrants pursuant to Regulation D 1,848,138   2,377 1,845,761  
Issuance of stock and warrants pursuant to Regulation D, shares     2,376,817    
Preferred stock/Debt conversions into common stock 367,500   490 367,010  
Preferred stock/Debt conversions into common stock, shares     490,000    
Net loss (10,005,631)       (10,005,631)
Ending Balance at Dec. 31, 2007 14,831,510   49,399 59,988,147 (45,206,036)
Ending Balance, shares at Dec. 31, 2007     49,399,281    
Issuance of warrants for services 517,820     517,820  
Exercise of warrants and stock options 2,639,711   3,268 2,636,443  
Exercise of warrants and stock options, shares     3,267,795    
Issuance of stock for services 390,000   350 389,650  
Issuance of stock for services, shares     350,000    
Employee compensation from stock options 1,946,066     1,946,066  
Net loss (10,269,571)       (10,269,571)
Ending Balance at Dec. 31, 2008 10,055,536   53,017 65,478,126 (55,475,607)
Ending Balance, shares at Dec. 31, 2008     53,017,076    
Issuance of warrants for services 1,064,210     1,064,210  
Exercise of warrants and stock options 2,524,453   3,480 2,520,973  
Exercise of warrants and stock options, shares     3,480,485    
Issuance of stock for services 695,000   796 694,204  
Issuance of stock for services, shares     796,012    
Employee compensation from stock options 870,937     870,937  
Issuance of stock and warrants pursuant to Regulation D 6,518,688   10,117 6,508,571  
Issuance of stock and warrants pursuant to Regulation D, shares     10,116,653    
Net loss (12,322,314)       (12,322,314)
Ending Balance at Dec. 31, 2009 9,406,510   67,410 77,137,021 (67,797,921)
Ending Balance, shares at Dec. 31, 2009     67,410,226    
Issuance of warrants for services 1,141,593     1,141,593  
Issuance of stock pursuant to Regulation S 419,250   559 418,691  
Exercise of warrants and stock options 3,103,680   3,491 3,100,189  
Issuance of stock pursuant to Regulation S, shares     559,000    
Exercise of warrants and stock options, shares     3,491,014    
Issuance of common stock and warrants pursuant to Regulation D 6,346,989   11,169 6,335,820  
Issuance of common stock and warrants pursuant to Regulation D, shares     11,168,067    
Issuance of preferred stock and warrants pursuant to Regulation D 4,217,390 13,283   4,204,107  
Issuance of stock for services 856,613   776 855,837  
Issuance of preferred stock and warrants pursuant to Regulation D, shares   13,283,324      
Issuance of stock for services, shares     776,250    
Employee compensation from stock options 3,759,650     3,759,650  
Preferred stock/Debt conversions into common stock   (7,893) 7,893    
Preferred stock/Debt conversions into common stock, shares   (7,893,326) 7,893,326    
Net loss (18,552,102)       (18,552,102)
Ending Balance at Dec. 31, 2010 10,699,573 5,390 91,298 96,952,908 (86,350,023)
Ending Balance, shares at Dec. 31, 2010   5,389,998 91,297,883    
Issuance of warrants for services 945,116     945,116  
Exercise of warrants and stock options 6,623,311   7,185 6,616,126  
Exercise of warrants and stock options, shares     7,185,522    
Issuance of common stock and warrants pursuant to Regulation D 7,041,239   9,905 7,031,334  
Sale of non-controlling interest in Pure-ific Corporation and warrants 443,500     443,500  
Issuance of common stock and warrants pursuant to Regulation D, shares     9,905,062    
Issuance of stock for services 332,750   350 332,400  
Issuance of stock for services, shares     350,000    
Employee compensation from stock options 3,368,950     3,368,950  
Preferred stock/Debt conversions into common stock   (1,859) 1,859    
Preferred stock/Debt conversions into common stock, shares   (1,858,333) 1,858,331    
Net loss (19,434,699)       (19,434,699)
Ending Balance at Dec. 31, 2011 10,019,740 3,531 110,597 115,690,334 (105,784,722)
Ending Balance, shares at Dec. 31, 2011   3,531,665 110,596,798    
Issuance of warrants for services 1,512,026     1,512,026  
Issuance of common stock and warrants pursuant to Regulation D 4,790,544   6,228 4,784,316  
Issuance of common stock and warrants pursuant to Regulation D, shares     6,227,647    
Issuance of stock for services 456,500   550 455,950  
Issuance of stock for services, shares     550,000    
Employee compensation from stock options 183,028     183,028  
Preferred stock/Debt conversions into common stock   (1,053) 1,053    
Preferred stock/Debt conversions into common stock, shares   (1,053,480) 1,053,480    
Net loss (12,568,354)       (12,568,354)
Ending Balance at Dec. 31, 2012 4,393,484 2,478 118,428 122,625,654 (118,353,076)
Ending Balance, shares at Dec. 31, 2012   2,478,185 118,427,925    
Issuance of warrants for services 1,527,518     1,527,518  
Exercise of warrants and stock options 21,000   44 20,956  
Exercise of warrants and stock options, shares     43,750    
Issuance of common stock and warrants pursuant to Regulation D 12,204,174   18,854 12,185,320  
Issuance of common stock and warrants pursuant to Regulation D, shares     18,854,470    
Issuance of preferred stock and warrants pursuant to Regulation D 1,252,050 3,400   1,248,650  
Issuance of stock for services 149,500   475 311,525  
Issuance of preferred stock and warrants pursuant to Regulation D, shares   3,400,001      
Issuance of stock for services, shares     475,000    
Employee compensation from stock options 142,310     142,310  
Dividends on preferred stock (29,063)     (29,063)  
Preferred stock/Debt conversions into common stock (29,063) (2,173) 2,173 (29,063)  
Preferred stock/Debt conversions into common stock, shares   (2,173,186) 2,173,186    
Net loss (11,100,250)       (11,100,250)
Ending Balance at Sep. 30, 2013 $ 8,723,223 $ 3,705 $ 139,974 $ 138,032,870 $ (129,453,326)
Ending Balance, shares at Sep. 30, 2013   3,705,000 139,974,331