Exhibit 99.4

The matters to be voted on at the Meeting are as follows. Unless you are appointing yourself to attend the Meeting and vote in person, please provide your voting instructions by marking the appropriate box. (see Note 1 overleaf) * SEE VOTING GUIDELINES ON REVERSE * RESOLUTIONS - MANAGEMENT VOTING RECOMMENDATIONS ARE INDICATED BY HIGHLIGHTED TEXT ABOVE THE BOXES 1. Election of Directors FOR WITHHOLD a) Adam Chowaniec b) Peter Copetti c) Sheldon Inwentash d) Ajit Manocha e) f) Samuel Peralta g) Geoffrey Taylor h) Chris Tsiofas 2. Appointment of Auditors FOR WITHHOLD Re-appoint Marcum LLP and authorize the directors to fix their remuneration. 3. Approval of Stock Option Plan FOR AGAINST To pass an ordinary resolution approving the amendments to the Company’s Stock Option Plan and approving the 2014 Plan as amended, with Insiders of the Company abstaining from voting, as set out in the Management Information Circular. 4. Adoption of Amendment to By-Law No. 1 FOR AGAINST To approve an ordinary resolution confirming the amendment to the Company's general By-Law 1, as set out in the Management Information Circular. 5. Approval of Consolidation of the Company’s Shares FOR AGAINST To consider and, if of one new common share for a maximum of five pre-consolidation shares and the accompanying Name Change, as set out in the accompanying Management Information Circular. 6. Approval and Ratification of Shareholders Rights Plan FOR AGAINST To consider and, if thought fit, to pass a special resolution approving and ratifying the Shareholders’ Rights Plan of the Company, as set out in the accompanying Management Information Circular. This VIF revokes and supersedes all earlier dated VIF and MUST BE SIGNED. Signature of Beneficial owner(s) Date (MM/DD/YYYY) PLEASE PRINT NAME POET TECHNOLOGIES INC. Company VOTING INSTRUCTION FORM (“VIF”) Annual General and Special Meeting 9:00 am EDT on August 12th, 2014 The Mansfield Room of the Nathan Hale Inn and Conference Center, 855 Bolton Road, Storrs-Mansfield, CT, USA (“Meeting”) The undersigned hereby appoints Peter Copetti, Executive Chairman and Interim CEO of the Company, whom failing Leon M. Pierhal, President, or failing both of them Michel J. Lafrance, Secretary (“Management Nominees”), or instead of any of them, the following Appointee as proxyholder on behalf of the undersigned with the power of substitution to attend, act and vote for and on behalf of the undersigned in respect of all matters that may properly come before the Meeting and at any adjournment(s) or postponement(s) thereof, to the same extent and with the same power as if the undersigned were personally present at the said Meeting or such adjournment(s) or postponement(s) thereof in accordance with voting instructions, if any, provided below. Please print appointee name RECORD DATE: July 2, 2014 CONTROL NUMBER: SEQUENCE #: FILING DEADLINE FOR VIF: 9:00 am EDT on August 8th, 2014 VOTING METHODS INTERNET Go to www.voteproxyonline.com and enter the 12 digit control number above FACSIMILE (416) 595-9593 MAIL or HAND DELIVERY TMX EQUITY TRANSFER SERVICES 200 University Avenue, Suite 300, Toronto, Ontario, M5H 4H1

Voting Instructions - Guidelines and Conditions The Company is providing you access to proxy-related materials for their security holder Meeting. Your name, address and information about your security holdings have been obtained in accordance with applicable securities regulations from the intermediary holding them on your behalf (which is identified by name, code or identifier in the information on the top left corner overleaf). The Voting Instruction Form (‘‘VIF’’) is to enable your vote to be submitted on the stated matters. Please complete, sign, date and return the VIF. Unless you appoint yourself or a delegate to attend the Meeting and vote, your securities can be voted only by Management Nominees in accordance with your instructions. We are prohibited from voting these securities on any of the matters to be acted upon at the Meeting without your specific voting instructions. The completed VIF should be delivered to TMX Equity Transfer Services, in the envelope provided or by fax to (416) 595-9593. Alternatively, if available, you may vote online at www.voteproxyonline.com. The matters to be voted on at the Meeting are set out overleaf. By providing voting instructions as requested, you are acknowledging that you are the beneficial owner of, and are entitled to instruct us with respect to the voting of, these securities. THIS VOTING INSTRUCTION FORM MUST BE READ IN CONJUNCTION WITH THE MEETING MATERIAL. YOUR VOTING INSTRUCTIONS MUST BE RECEIVED NO LATER THAN THE DEADLINE SPECIFIED OVERLEAF IN THE UPPER RIGHT SECTION OF THE VIF OR THE EQUIVALENT TIME BEFORE THE TIME AND DATE OF ANY ADJOURNMENT OF THE MEETING. Voting Instructions and Authority - Notes 1. If you appoint the Management Nominees to vote your securities, they will vote in accordance with your instructions or, if no instructions are given, in accordance with the Management Voting Recommendation highlighted for each Resolution overleaf. If you appoint someone else to vote your securities, they will also vote in accordance with your instructions or, if no instructions are given, as they in their discretion choose. 2. The appointment of the Management Nominees or another Appointee gives them discretion to vote on any other matters that may properly come before the Meeting. 3. If Internet voting is available, you can provide your voting instructions on the website noted overleaf. 4. To be valid, this VIF must be signed. Please date the VIF. If the VIF is not dated, it is deemed to bear the date of its being mailed to the security holders of the Company. 5. This form does not convey any right to vote in person at the Meeting. We urge you to read the above instructions, and the Information Circular prior to completing, signing and returning the VIF so that your securities can be voted. For assistance, please contact TMX Equity Transfer Services: Mail: Telephone: Facsimile: Email: TMX Equity Transfer Services 200 University Avenue, Suite 300 Toronto, ON M5H 4H1 (416) 361-0930 (416) 595-9593 investor@equityfinancialtrust.com Appointing yourself or someone else to vote your securities If you want to attend the Meeting and vote in person at the Meeting or appoint another person to do so, write your name or the name of the person attending the Meeting in the space labeled Please print appointee name on the VIF and return it. Unless prohibited by law, the person whose name is written in the space provided will have full authority to present matters to the Meeting and vote on all matters that are presented at the Meeting, even if those matters are not set out in this form or the information circular. Consult a legal advisor if you wish to modify the authority of that person in any way. When you or your Appointee arrives at the Meeting, they should give their name to the scrutineers and state that they are a proxy appointee. The Appointee must attend the Meeting in order for your shares to be voted. Notice-and-Access The Canadian securities regulators have adopted new rules, effective for meetings held on or after March 1, 2013, which permit the use of notice-andaccess for proxy solicitation instead of the traditional physical delivery of material. This new process provides the option to post meeting related materials including management information circulars as well as annual financial statements and management’s discussion and analysis, on a website in addition to SEDAR. Under notice-and-access, meeting related materials will be available for viewing for up to 1 year from the date of posting and a paper copy of the material can be requested at any time during this period. Disclosure regarding each matter or group of matters to be voted on is in the Information Circular in the Section with the same title as each Resolution overleaf. You should review the Information Circular before voting. POET TECHNOLOGIES INC. has elected to utilize notice-and-access and provide you with the following information: Meeting materials are available electronically at www.sedar.com and also at www.poet-technologies.com/agm2014. If you wish to receive a paper copy of the Meeting materials or have questions about notice-and-access, please call 1-866-393-4891. In order to receive a paper copy in time to vote before the meeting, your request should be received by August 1, 2014. TMXEquityTransferServices.com VANCOUVER CALGARY TORONTO MONTRÉAL Request for Financial Statements In accordance with securities regulations, security holders may elect to receive Annual Financial Statements, Interim Financial Statements, and MD&As. Instead of receiving the financial statements by mail, you may choose to view these documents on SEDAR at www.sedar.com. I am a security holder of the Company, and as such request the following: If you are casting your vote online and wish to receive financial statements, please complete the online request for financial statements following your voting instructions. If the cut-off time has passed, please fax this side to 416-595-9593. E-MAIL (optional) By providing my email address, I hereby acknowledge and consent to all provisions outlined in the following: https://www.voteproxyonline.com/equity/fsred.pdf POET TECHNOLOGIES INC. FISCAL YEAR 2014 Annual Financial Statements with MD&A (Mark this box if you would like to receive the Annual Financial Statements and related MD&A) Interim Financial Statements with MD&A (Mark this box if you would like to receive the Interim Financial Statements and related MD&A) Check this box if you wish to receive the selected financial statements electronically and print your email address below E-MAIL (optional)