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Derivative Financial Instruments (Details) (USD $)
3 Months Ended 12 Months Ended
Dec. 31, 2013
MMBTU
Sep. 30, 2013
Jun. 30, 2013
Mar. 31, 2013
Dec. 31, 2012
MMBTU
Sep. 30, 2012
Jun. 30, 2012
Mar. 31, 2012
Dec. 31, 2013
MMBTU
Dec. 31, 2012
MMBTU
Dec. 31, 2011
Fair values of derivatives on consolidated balance sheets                      
Maximum period covering risk of changes in supply of gas prices                 18 months    
Open derivative contracts for natural gas (in MMBtus) 76,300,000       58,900,000       76,300,000 58,900,000  
Percentage of natural gas consumption covered by derivatives                 90.00%    
Aggregate fair value of the derivative instruments with credit risk related contingent features in a net liability position $ 200,000       $ 900,000       $ 200,000 $ 900,000  
Authorized expenditure for construction of new ammonia and urea/UAN production units         3,800,000,000         3,800,000,000  
Unrealized gains (losses)                      
Derivatives not designated as hedges                 67,700,000 72,800,000 (77,300,000)
Cash flow hedge ineffectiveness                 (1,800,000) 1,800,000  
Total unrealized gains (losses) 55,800,000 15,700,000 (14,400,000) 8,800,000 13,100,000 39,800,000 77,600,000 (55,900,000) 65,900,000 74,600,000 (77,300,000)
Realized gains (losses)                 1,800,000 (144,400,000) (54,500,000)
Net derivative gains (losses)                 67,700,000 (69,800,000) (131,800,000)
Cash collateral on deposit with derivative counterparties 0       0       0 0  
Foreign exchange contracts
                     
Fair values of derivatives on consolidated balance sheets                      
Notional amount of derivative 636,300,000               636,300,000    
Derivatives not designated as cash flow hedges
                     
Unrealized gains (losses)                      
Derivatives not designated as hedges                 67,700,000 72,800,000 (77,300,000)
Derivatives not designated as cash flow hedges | Natural gas derivatives
                     
Unrealized gains (losses)                      
Derivatives not designated as hedges                 52,900,000 66,500,000 (77,300,000)
Derivatives not designated as cash flow hedges | Foreign exchange contracts
                     
Unrealized gains (losses)                      
Derivatives not designated as hedges                 14,800,000 6,300,000  
Derivatives designated as cash flow hedges | Foreign exchange contracts
                     
Fair values of derivatives on consolidated balance sheets                      
Notional amount of derivative 0               0    
Net gain (loss) expected to be reclassified into earnings from AOCI                 0 0 0
Gain (loss) recognized in OCI                 3,000,000 7,200,000  
Unrealized gains (losses)                      
Net derivative gains (losses)                 $ (1,800,000) $ 1,800,000