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Segment Information (Total Assets) (Details) - USD ($)
$ in Thousands
Sep. 30, 2015
Dec. 31, 2014
Segment Reporting, Asset Reconciling Item [Line Items]    
Total assets $ 5,524,405 $ 5,213,990
Olefins    
Segment Reporting, Asset Reconciling Item [Line Items]    
Total assets 1,817,303 1,785,895
Vinyls    
Segment Reporting, Asset Reconciling Item [Line Items]    
Total assets 2,601,263 2,618,646
Corporate and Other    
Segment Reporting, Asset Reconciling Item [Line Items]    
Total assets $ 1,105,839 $ 809,449