Exhibit 32.1

Certification Pursuant to

18 U.S.C. Section 1350

by Chief Executive Officer

In connection with the Annual Report of VSB Bancorp, Inc. (the “Company”) on Form 10-K for the period ending December 31, 2012, as filed with the Securities and Exchange Commission on or about the date hereof (the “Report”), I, Raffaele M. Branca, President and Chief Executive Officer of the Company, certify, pursuant to 18 U.S.C. Section 1350, that:

(1) The Report fully complies with the requirements of section 13(a) or 15(d) of the Securities Exchange Act of 1934; and

(2) The information contained in the Report fairly presents, in all material respects, the financial condition and results of operations of the Company.

Date: March 15, 2013

/s/Raffaele M. Branca

Raffaele M. Branca

President and CEO

A signed original of this written statement has been provided to the Company and will be retained by the Company and furnished to the Securities and Exchange Commission or its staff upon request.